http://hearthstone.gamepedia.com/QuestCompleting the one time "Unique quests"(also call hidden quest)
when you have more then 2 same cards, Dischant the 3rd for "Crafting Time" quest (Disenchant a card: Earn 95 arcane dust) because you deck only allow maximun 2 indentical card, since you can't use it anyway
in my begining days, i made a mistake thinking DE a blue(which i though it was useless at the time) and get the dust to craft another blue(which i deem useful) is a good trade. wrong, (but i was desperate for a good card), now that blue card is let to rot in my collection

i assume you have clear all classes(vs AI) with your mage/paladin to unlock all 9 classes,
if you are going for expert mode for Crush Them All! quest(Defeat every Expert AI Hero: reward 100 gold)
i suggest you do it in a sequence, so you won't forget which hero you haven't defeat.
my advice for beginner is "Legendary cards doesn't win game (but it help alot)"
in my early days, i always fear legendary cards for i have none, heck i don't even have epic card, but i learn to play smart. and when i win, it feel awesome.
I guess I don't have any same cards more than 2 for now. Later maybe.
Yeah, I have clear all the classes which some I unlock in Casual/Rank and some in Practice Normal mode.
I still don't very clear on the type of cards. Maybe I will as I play along.